Periodate Oxidation of Some Carbohydrates as Examined by NMR Spectroscopy
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چکیده
منابع مشابه
Quantitative Determination of Dihydrostreptomycin by Periodate Oxidation.
Dihydrostreptomycin is produced commercially by the catalytic hydrogenation of streptomycin. The reaction involves the reduction of the aldehyde group in the streptose moiety of the streptomycin molecule to the corresponding primary carbinol group as evidenced by the failure of dihydrostreptomycin to react with carbonyl reagents or with alkali to produce maltol. As there are no chemical methods...
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The inhibitory effects of a number of periodate-oxidation products of carbohydrates and carbohydrate derivatives were studied on various transplanted tumors in mice and on a variety of microorganisms. Many of the compounds showed striking inhibition of Ehrlich ascites and inhibition of Leukemia L1210 in mice. The compounds were not active against Sarcoma 180 and Adenocarcinoma 755 or against an...
متن کاملPartial oxidation of light alkanes by periodate and chloride salts.
The efficient and selective partial oxidation of light alkanes using potassium periodate and potassium chloride is reported. Yields of methane functionalization in trifluoroacetic acid reach >40% with high selectivity for methyl trifluoroacetate. Periodate and chloride also functionalize ethane and propane in good yields (>20%).
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ژورنال
عنوان ژورنال: Agricultural and Biological Chemistry
سال: 1974
ISSN: 0002-1369
DOI: 10.1080/00021369.1974.10861527